This work reports on a novel, facile synthetic methodology into the telluro
phene nucleus, which was applied in particular to the synthesis of the cent
rosymmetrical 2, 5-bis(3-butyl-2-thienyl)tellurophene. Thereafter, oxidativ
e polymerization of the monomer using iron (III) chloride afforded the regi
oregular poly[2,5-bis(3-butyl-2-thienyl)tellurophene]. Preliminary characte
rization aspects of the polymer are reported.