N. Kimizuka et al., Spatially controlled synthesis of protein/inorganic nano-assembly: Alternate molecular layers of cyt c and TiO2 nanoparticles, CHEM LETT, (12), 1999, pp. 1333-1334
A molecular layer of Cytochrome c was self-assembled on two-dimensionally a
ccumulated TiO2 nanoparticles, that have been deposited by hydrolysis of ti
tanium hexafluoride in water. Repeated cycles of TiO2-deposition and cyt c-
adsorption from aqueous phases afforded multilayered nano-assemblies, in wh
ich native spectral characteristics of cyt c was preserved.