The challenge during the characterization of nanostructures is in extractin
g consistent local and spatially varying information from the structure and
correlating it to the new physics that appears at the nanoscale. Recent ye
ars have seen exciting advances in imaging and spectroscopy techniques that
can achieve this goal. The techniques offer the possibility to directly in
vestigate local properties of materials with sub-nanometre spatial resoluti
on. In this paper we review, from the perspective of our own contributions
to the field of carbon nanostructures, recent advances in the application o
f nanoanalysis. Complementary techniques of spatially resolved electron, an
d scanning tunneling microscopy and spectroscopy, can be used to characteri
ze and correlate the structure, topology, chemistry and electronic properti
es of nanostructures. Often the interpretation of the data needs to come fr
om comparison with adequate theoretical models. (C) 1999 Elsevier Science L
td. All rights reserved.