N,O-polydentate scorpionate ligands

Authors
Rheingold, AL Haggerty, BS Liable-Sands, LM Trofimenko, S
Citation
Al. Rheingold et al., N,O-polydentate scorpionate ligands, INORG CHEM, 38(26), 1999, pp. 6306
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
26
Year of publication
1999
Database
ISI
SICI code
0020-1669(199912)38:26<6306:NSL>2.0.ZU;2-G
Abstract
New bis- and trispyrazolylborate (scorpionate) ligands derived from 3-(2,4- dimethoxyphenyl)pyrazole have been synthesized. They can function as N,O-po lydentate donors, as was demonstrated in the structure of the octahedral co mplex Ni[Bp((2,4(OMe)2Ph))](2). The structure of Tl[Tp((2,4(OMe)2Ph))] has also been determined.