Synthesis and structural characterization of [RuCl2(CO)(2)(TePh2)(2)]center dot 1/2C(6)H(6)

Authors
Oilunkaniemi, R Laitinen, RS Ahlgren, M
Citation
R. Oilunkaniemi et al., Synthesis and structural characterization of [RuCl2(CO)(2)(TePh2)(2)]center dot 1/2C(6)H(6), INORG CH C, 3(1), 2000, pp. 8-10
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
1
Year of publication
2000
Pages
8 - 10
Database
ISI
SICI code
1387-7003(200001)3:1<8:SASCO[>2.0.ZU;2-Y
Abstract
The reaction of Ph2Te with [RuCl2(CO)(3)](2) affords a monomeric ruthenium complex [RuCl2(CO)(2)(TePh2)(2)]. The X-ray structure shows the formation o f the trans(Ph2Te), cis(Cl), cis(CO) isomer. The C-13 NMR and Te-125 NMR sp ectra of the complex an reported. (C) 2000 Elsevier Science S.A. All rights reserved.