Reactions of platinum(II)-nitrile complexes with amines. Synthesis, characterization and X-ray structure of the platinum (II)-amidine complex trans-[PtCl2{Z-N(H)=C(NHMe)Me}(2)]

Authors
Bertani, R Catanese, D Michelin, RA Mozzon, M Bandoli, G Dolmella, A
Citation
R. Bertani et al., Reactions of platinum(II)-nitrile complexes with amines. Synthesis, characterization and X-ray structure of the platinum (II)-amidine complex trans-[PtCl2{Z-N(H)=C(NHMe)Me}(2)], INORG CH C, 3(1), 2000, pp. 16-18
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
1
Year of publication
2000
Pages
16 - 18
Database
ISI
SICI code
1387-7003(200001)3:1<16:ROPCWA>2.0.ZU;2-9
Abstract
The reaction of trans-[PtCl2(NCMe)(2)] with a 5-fold excess of MeNH2 in CH2 Cl2 at -10 degrees C affords in high yield the bis-amidine complex trans-[P tCl2{Z-N(H) = C(NHMe)Me}(2)] (1),where both the amidine ligands assume the Z configuration corresponding to the trans addition of the amine along the C = N triple band. Compound I has been fully characterized by spectroscopic techniques and also by X-ray diffraction analysis. (C) 2000 Elsevier Scien ce S.A. All rights reserved.