Novel ferrocene derived cyclocarbaphosphazenes: Synthesis and structure ofspiro {Fe(eta-C5H5)-[eta-C5H4CH2P(S) (CH2O)(2)PN]} (Me2NCN)(2)

Authors
Reddy, ND Elias, AJ Vij, A
Citation
Nd. Reddy et al., Novel ferrocene derived cyclocarbaphosphazenes: Synthesis and structure ofspiro {Fe(eta-C5H5)-[eta-C5H4CH2P(S) (CH2O)(2)PN]} (Me2NCN)(2), INORG CH C, 3(1), 2000, pp. 29-31
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
1
Year of publication
2000
Pages
29 - 31
Database
ISI
SICI code
1387-7003(200001)3:1<29:NFDCSA>2.0.ZU;2-D
Abstract
The first examples of ferrocene derived cyclocarbaphosphazenes have been sy nthesized by the reaction of Fe(eta-C5H5)-[eta-C5H4CH2P(S) (CH2OLi)(2)] wit h (RR'NCN)(2)(Cl2PN) [RR'N = Me2N and PhCH2(Me)N]. The crystal structure of the spirocyclic compound {Fe(eta-C5H5)-[eta-C5H4CH2P(S) (CH2O)(2)PN)]}(Me2 NCN)(2) has been determined and shows an axial orientation of the ferroceny lmethyl group with respect to the six-membered chair form of the spirocycle . (C) 2000 Elsevier Science S.A. All rights reserved.