Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc

Citation
T. Shibata et al., Highly enantioselective catalytic isopropenylation of aldehydes using diisopropenylzinc, INORG CHIM, 296(1), 1999, pp. 33-36
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
296
Issue
1
Year of publication
1999
Pages
33 - 36
Database
ISI
SICI code
0020-1693(199912)296:1<33:HECIOA>2.0.ZU;2-I
Abstract
Diisopropenylzinc adds highly enantioselectively to various aldehydes in th e presence of a catalytic amount of chiral amino alcohols to give enantiome rically enriched allyl alkanols with up to 92% e.e. (C) 1999 Elsevier Scien ce S.A. All rights reserved.