Synthesis and catalytic oxidation properties of polymer-bound cobalt complexes

Authors
Lei, ZQ Han, XG Hu, YL Wang, RM Wang, YP
Citation
Zq. Lei et al., Synthesis and catalytic oxidation properties of polymer-bound cobalt complexes, J APPL POLY, 75(8), 2000, pp. 1068-1074
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science","Material Science & Engineering
Journal title
JOURNAL OF APPLIED POLYMER SCIENCE
ISSN journal
00218995 → ACNP
Volume
75
Issue
8
Year of publication
2000
Pages
1068 - 1074
Database
ISI
SICI code
0021-8995(20000222)75:8<1068:SACOPO>2.0.ZU;2-0
Abstract
Polymer-bound 2,2'-bipyridine cobalt complexes PSBPY-Co, PSBPY-Co-bipy, PSB PY-Co-oxine, and PSBPY-Co-phen (where PSBPY: polystyrene bound-2,2'-bipyrid ine; bipy: 2,2'-bipyridine; phen: 1,10-phenanthroline) were synthesized and investigated by IR, X-ray photoelectric spectroscopy, thermogravimetry-dif ferential thermal analysis, inductively coupled plasma atomic emission spec trometry, and elemental analysis. The complexes mere found to be catalysts for the oxidation of alkylbenzenes and cyclohexene in the presence of molec ular oxygen in the absence of solvent. (C) 2000 John Wiley & Sons, Inc.