Rescaling of diffusion coefficients in two-time scale chemical systems

Citation
De. Strier et Sp. Dawson, Rescaling of diffusion coefficients in two-time scale chemical systems, J CHEM PHYS, 112(2), 2000, pp. 825-834
Citations number
34
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
112
Issue
2
Year of publication
2000
Pages
825 - 834
Database
ISI
SICI code
0021-9606(20000108)112:2<825:RODCIT>2.0.ZU;2-G
Abstract
We study reaction-diffusion systems which involve processes that occur on d ifferent time scales. In particular, we apply a multiscale analysis to obta in a reduced description of the slow dynamics. Under certain assumptions th is reduction yields a new set of reaction-diffusion equations with rescaled diffusion coefficients. We analyze the Selkov model [E. E. Selkov, Eur. J. Biochem. 4, 79 (1968)] and the ferrocyanide-iodide-sulfite reaction [E. C. Edblom et al., J. Am. Chem. Soc. 108, 2826 (1986)] to determine whether th e rescaling in this case may account for the difference of diffusivities th at the formation of certain types of patterns requires. (C) 2000 American I nstitute of Physics. [S0021-9606(99)51848-5].