The synthesis of perfluoroamine using nitrogen trifluoride

Authors
Takagi, T Tamura, M Shibakami, M Quan, HD Sekiya, A
Citation
T. Takagi et al., The synthesis of perfluoroamine using nitrogen trifluoride, J FLUORINE, 101(1), 2000, pp. 15-17
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
101
Issue
1
Year of publication
2000
Pages
15 - 17
Database
ISI
SICI code
0022-1139(200001)101:1<15:TSOPUN>2.0.ZU;2-V
Abstract
The reactions of nitrogen trifluoride (1) with hexafluoropropene (2) in the presence of cesium fluoride (CsF) gave 2- (3) and 1-heptafluoropropyldiflu oroamine (4) in moderate yields. Tetrafluoroethylene (6) and octafluoro-2-b utene (8) similarly reacted with 1 to give corresponding products. (C) 2000 Elsevier Science S.A. All rights reserved.