Fluorodesulfurization of beta,beta-bis(methylthio)-alpha,beta-unsaturated carbonyl compounds. Synthesis of beta,beta-difluoro-beta-(methylthio) carbonyl compounds

Authors
Hara, S Ohmori, A Fukuhara, T Yoneda, N
Citation
S. Hara et al., Fluorodesulfurization of beta,beta-bis(methylthio)-alpha,beta-unsaturated carbonyl compounds. Synthesis of beta,beta-difluoro-beta-(methylthio) carbonyl compounds, J FLUORINE, 101(1), 2000, pp. 35-38
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
101
Issue
1
Year of publication
2000
Pages
35 - 38
Database
ISI
SICI code
0022-1139(200001)101:1<35:FOBC>2.0.ZU;2-H
Abstract
beta,beta-Bis(methylthio)vinyl carbonyl compounds (1) reacted with pyridine -6HF and Hg(OCOCF3)(2) to give beta,beta-difluoro-beta-(methylthio) carbony l compounds (2) in good yield. (C) 2000 Elsevier Science S.A. All rights re served.