Gd. Del Cul et al., Some investigations of the reaction of activated charcoal with fluorine and uranium hexafluoride, J FLUORINE, 101(1), 2000, pp. 137-148
Since the 1969 shutdown of the Molten Salt Reactor Experiment (MSRE) at Oak
Ridge, radiolytically generated fluorine (F-2) and 233-uranium hexafluorid
e ((UF6)-U-233) migrated from the fuel storage tanks through gas piping to
a charcoal bed. This report addresses the carbon-fluorine-uranium chemistry
under conditions reproducing those found in the charcoal beds. Laboratory
analysis of the reaction products has been extensive and includes electron
spectroscopy for chemical analysis (ESCA), nuclear magnetic resonance (NMR)
, FTIR and Raman spectroscopy, TGA-DTA as well as a host of other technique
s. The chemical identity, stoichiometry, structure, thermochemistry, and po
tential for energetic decomposition of the primary reaction product, 'fluor
inated charcoal', was determined. As a result of this research, remedial so
lutions were developed and implemented. (C) 2000 Elsevier Science S.A. All
rights reserved.