Statement of problem. Acid etching creates retentive microcraters on e
namel surfaces. Designing of a partial denture often involves reshapin
g the supporting and retentive teeth by grinding the enamel. Unfortuna
tely, both these procedures damage the enamel surface. In vivo such su
rface damage takes several months to recover. Purpose. This study eval
uated the effect of 1-minute etching, prolonged etching, and grinding
on the permeability of dental enamel for water-soluble molecules. Mate
rial and methods. With the electron paramagnetic resonance and a two-c
hamber diffusion cell, the influence of etching and grinding on the di
ffusion of spin label molecules through the enamel was studied quantit
atively. The enamel permeability was measured in 30 sound enamel sampl
es, of which 10 samples were exposed to 1-minute etching with 37% phos
phoric acid, 10 samples were etched for 5 minutes, and 10 samples were
ground with a diamond bur. Results and Conclusions. All procedures si
gnificantly increased the permeability of dental enamel. These results
demonstrate that in vivo the acid-etched and ground dental enamel sur
faces are less protected and consequently, unless the tooth is properl
y protected, are more susceptible to carious lesions. Therefore ground
or accidentally etched enamel should be protected.