M. Bohner et al., Effect of several additives and their admixtures on the physico-chemical properties of a calcium phosphate cement, J MAT S-M M, 11(2), 1999, pp. 111-116
Citations number
18
Categorie Soggetti
Multidisciplinary
Journal title
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE
Combinations of citrate (C6H5O73-), pyrophosphate (P2O74-) and sulfate (SO4
2-) ions were used to modify the physico-chemical properties of a calcium p
hosphate cement (CPC) composed of beta-tricalcium phosphate (beta-TCP) and
phosphoric acid (PA) solution. The results obtained with only one additive
at a time are similar to those previously published. New facts are: the pos
itive effect of C6H5O73- ions on cement failure strain and their negative e
ffect on cement pH. The position of the setting time maximum measured at an
SO42- concentration of 0.09 M was not displaced by the addition of C6H5O73
- and P2O74- ions. However, the effect of SO42- ions on the setting time wa
s depressed by C6H5O73- ions. Moreover, no increase in tensile strength was
observed when increasing amounts of SO42- were added into a C6H5O73--conta
ining cement. The latter results suggest a competitive effect of C6H5O73- a
nd SO42- on setting time and tensile strength. Anhydrous dicalcium phosphat
e (DCP; CaHPO4) appeared in cement samples dried just after setting, but no
t in cement samples incubated for 24 h in deionized water before the drying
step. It is believed that the setting reaction is stopped by the drying st
ep, leaving a low internal pH in the sample, hence providing favorable cond
itions for the transformation of dicalcium phosphate dihydrate (DCPD) into
DCP. Interestingly, even though C6H5O73- ions dramatically lowered the equi
librium pH of the cement with 5 ml of deionized water, they still prevented
the occurrence of the transformation of DCPD into DCP. (C) 2000 Kluwer Aca
demic Publishers.