Algebraic derivation of Franck-Condon overlap integrals for diatomic molecules

Authors
Frank, A Lemus, R Perez-Bernal, F
Citation
A. Frank et al., Algebraic derivation of Franck-Condon overlap integrals for diatomic molecules, J MATH CHEM, 25(4), 1999, pp. 383-391
Citations number
31
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF MATHEMATICAL CHEMISTRY
ISSN journal
02599791 → ACNP
Volume
25
Issue
4
Year of publication
1999
Pages
383 - 391
Database
ISI
SICI code
0259-9791(1999)25:4<383:ADOFOI>2.0.ZU;2-U
Abstract
We derive a new formula for Franck-Condon harmonic-oscillator overlap integ rals using an algebraic procedure based on a Bogoliubov transformation. We discuss how the formulation may be generalized to SU(2)-based descriptions of anharmonic oscillator wave functions.