Synthesis of dioxazaborocines from N-substituted-bis(2-hydroxyaryl)aminomethylamines

Authors
Woodgate, PD Horner, GM Maynard, NP Rickard, CEF
Citation
Pd. Woodgate et al., Synthesis of dioxazaborocines from N-substituted-bis(2-hydroxyaryl)aminomethylamines, J ORGMET CH, 592(2), 1999, pp. 180-193
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
592
Issue
2
Year of publication
1999
Pages
180 - 193
Database
ISI
SICI code
0022-328X(199912)592:2<180:SODFN>2.0.ZU;2-4
Abstract
The preparation of a number of tripodal amines from aminoalkylation of 1,3- benzoxazines by phenols is presented. A series of ligands prepared in this manner were successfully coordinated to boron, giving dioxazaborocines. X-r ay crystal structures of two analogues are reported. These compounds are ca pable of releasing berate ions and are therefore potentially biologically a ctive. (C) 1999 Elsevier Science S.A. All rights reserved.