Anisotropic coarsening of two-dimensional surface domains in copolymer thin films

Citation
J. Heier et al., Anisotropic coarsening of two-dimensional surface domains in copolymer thin films, MACROMOLEC, 32(26), 1999, pp. 9007-9012
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULES
ISSN journal
00249297 → ACNP
Volume
32
Issue
26
Year of publication
1999
Pages
9007 - 9012
Database
ISI
SICI code
0024-9297(199912)32:26<9007:ACOTSD>2.0.ZU;2-X
Abstract
We have investigated by scanning force microscopy the growth of surface rel ief structures on thin diblock copolymer films for a infinity x infinity ge ometry (homogeneous substrate) and a L x infinity geometry (heterogeneous s ubstrate). We characterize the growth by a length scale obtained from the c orrelation function describing the fluctuations. Two-dimensional viscous fl ow within a continuous layer dominates the process. On the homogeneous subs trate we find a power law growth with an exponent of alpha = 2/3, while the growth on the stripe pattern in a direction parallel to the stripes is cha racterized by an exponent that is much lower.