The measurement of d.c. electrical conductivity of the bulk samples of chal
cogenide glasses of the system Ge10+xSe40Te50-x (x = 0.0, 13.35, 16.65 at.%
) are studied. The activation energies are obtained from conductivity measu
rements, using Mott and Davis equation. The relationship between the energy
of decomposition Ed and composition is discussed in terms of the average h
eat of atomization. The effect of heat treatment on the structure transform
ation is investigated by X-ray diffraction and scanning electron microscope
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