New materials, containing nanodispersed particles (Ag, Pb, Mn, Ca, Sm, Na,
CdS, ZnS) in the thin polymer film have been obtained via low temperature c
odeposition of metal (or sulphide) with reactive para-xylylene monomer vapo
urs at 100 K. Electric conductivity of the films was studied during the com
ponents co-condensation, upon sample annealing in range 80-300 K and mainta
ining at constant temperature. With a rise of metal nanoparticles in the po
lymer matrix, the conductivity tends to increase. The conductivity may be d
etermined as a tunnel transfer of charge from one nanoparticle to another t
hrough a thin dielectric layer (up to 50 nm) of polymer matrix. (C) 1999 El
sevier Science S.A. All rights reserved.