Synthesis and monolayer study of a new amphiphilic photochromic crown-ether

Citation
Sy. Zaitsev et al., Synthesis and monolayer study of a new amphiphilic photochromic crown-ether, MAT SCI E C, 8-9, 1999, pp. 469-473
Citations number
5
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS
ISSN journal
09284931 → ACNP
Volume
8-9
Year of publication
1999
Pages
469 - 473
Database
ISI
SICI code
0928-4931(199912)8-9:<469:SAMSOA>2.0.ZU;2-G
Abstract
The ionoselective and photosensitive properties of the new amphiphilic crow n-ether dye {perchlorate of 2-[(E)-2-(2,3,5,6,8,9,11,12-octahydro- 1,4,7,10 ,13-benzopentaoxacyclopentadecin-15-yl)]-5-octadecanoylamino-3-ethyl-1,3-be nzothiazolium} in monolayers have been studied. The collapse pressure of th e dye monolayers is about 53 mN/m on distilled water, slightly increases up to 57-59 mN/m in the presence of Na+, Ca2+, Mg2+ cations and significantly decreases up to 43-44 mN/m in the presence of K+ cations in the aqueous su bphases. The area per dye molecule in monolayer is the smallest on water an d increases with increasing of the salt concentration in the aqueous subpha se. These are evidences for the existence of the dye-cation complexes in mo nolayers. The reversible changes of the reflection intensity (irans-cis-tra ns isomerization) by dye photoactivation can be observed only for the dye-c ation complexes at very low surface pressure in the liquid-expanded state o f monolayers. The changes of the reflection intensity by photoactivation in the Liquid-condensed state of the dye monolayers on KCl solution are found irreversible that may be due to the photodimerization of the dye to cyclob utane. (C) 1999 Elsevier Science S.A. All rights reserved.