Chemical compositions, crystallography, microstructure and phase transforma
tion behavior of TiNi-base alloy films grown by R.F. magnetron sputtering h
ave been investigated. Effects of alloying elements such as Cu and Fe on fi
lm crystallography and properties are studied. Due to the non-equilibrium c
haracteristic of sputter deposition, as-deposited TiNi-base films prepared
are in a non-equilibrium, amorphous state. To yield crystalline structures
and desirable phase transformation behaviors, post-deposition annealing in
vacuum at 600 degrees C for 1 h is needed. Phase transformation behavior is
evaluated by a differential scanning calorimeter and results indicate a ty
pical single-stage transformation in annealed binary films (Ti-48.9 at.%Ni
and Ti-41.8Ni). For the Ti-36.6Ni-10.4Cu film, a two-stage transformation i
s revealed. The single-stage transformation takes place between the B2 pare
nt phase and M (monoclinic) martensite or R (rhombohedral) phase, while the
two-stage transformation occurs in a sequence of B2 phase to O (orthorhomb
ic) phase to M phase on cooling and vice versa on heating. Yet, an imperfec
t phase transformation is found in the Ti-45.4Ni-6.3Fe film for the tempera
ture range examined. Transformation temperatures as well as energies involv
ed in the transformations are in general relatively lower than those of the
target. Transformation peak-temperature hystereses of the film are also sm
aller than that of the target, implying a beneficial characteristic of fast
response for shape memory effect. (C) 2000 Elsevier Science S.A. All right
s reserved.