Citation
Va. Maksakov et al., Transformation of diaminocarane on a triosmium cluster. Absolute configuration of a cluster with a bridging imidyl ligand, MENDELEEV C, (6), 1999, pp. 213-214
Citations number
14
Categorie Soggetti
Chemistry
Journal title
MENDELEEV COMMUNICATIONS
ISSN journal
09599436
→ ACNP
Issue
6
Year of publication
1999
Pages
213 - 214
Database
ISI
SICI code
0959-9436(1999):6<213:TODOAT>2.0.ZU;2-6
Abstract
The C-H activation of an NMe2 group in diaminocarane coordinated to an Os-3
cluster results in the formation of (R,S)-{Os-3(CO)(10)(mu- H){mu,eta(2)(N
,C)- (4R,6R,8S,10S)-1,7,7,10-tetramethyl-1,3-diazatricyclo[3.5.0.0]dec-1-en
-2-yl}} diastereomers.