The structure of powder phosphorus steels is investigated. New models of is
othermal decomposition of supercooled austenite are suggested which make it
possible to predict the kinetics of the gamma --> alpha transformation in
the pearlite and bainite temperature ranges. It is shown that mechanical al
loying has a favorable effect on the formation of structure in steels. Grai
n disintegration accelerates the decomposition of austenite mainly due to t
he growth of the specific surface. Ar the same time,: the contribution of 0
.65 - 1.1% phosphorus additives to the process is low.