Cyclometalated complexes with triphosphine ligands: A novel route for promoting pentacoordination in palladium(II)

Authors
Vila, JM Pereira, MT Ortigueira, JM Fernandez, JJ Fernandez, A Lopez-Torres, M Adams, H
Citation
Jm. Vila et al., Cyclometalated complexes with triphosphine ligands: A novel route for promoting pentacoordination in palladium(II), ORGANOMETAL, 18(26), 1999, pp. 5484-5487
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
26
Year of publication
1999
Pages
5484 - 5487
Database
ISI
SICI code
0276-7333(199912)18:26<5484:CCWTLA>2.0.ZU;2-#
Abstract
The palladium(II) compound [Pd{3,4-(MeO)(2)C6H2C(H)=NCy}{(Ph2PCH2CH2)(2)PPh -P,P,P}]-[PF6] was synthesized and characterized by elemental analysis (C, H, N) and by H-1 and P-31{H-1} NMR spectroscopy in CDCl3 and P-31{H-1} soli d-state NMR spectroscopy. The molecular structure was determined by X-ray c rystallography, showing it to be the first pentacoordinated cyclometalated palladium(II)complex.