Lag synchronization denotes a particular form of synchronization in which t
he amplitudes of two interacting, nonidentical chaotic oscillators are corr
elated but there is a characteristic time delay between them. We study tran
sitions to and between different forms of synchronization for the attractor
s defined as "in-phase" and "out-of-phase" and investigate the processes by
which lag synchronization is lost in two coupled Rossler systems. With a s
mall frequency mismatch between the two systems, these processes are relate
d to the occurrence of a peculiar form of basin structure as more and more
periodic orbits embedded into the synchronized chaotic state become unstabl
e in a transverse direction. [S1063-651X(99)03711-3].