The velocity distribution of atoms in an exosphere can be used to constrain
source and loss processes. The velocity distribution itself can be constra
ined by observing the line profile of an atmospheric emission line, The onl
y atomic species known to exist in the Hermean exosphere that has a strong
enough resonance transition in the visible spectrum that its line profile c
an be observed from the ground with existing instruments is sodium. Line pr
ofiles of the sodium D2 emission (5889 A) were obtained at two facilities.
On 29 and 30 May 1997, we obtained line profiles with the 107 inch telescop
e at The McDonald Observatory at coude focus. On 6 January 1998, we obtaine
d line profiles at the Anglo-Australian telescope. The line profiles show t
hat the sodium in Mercury's atmosphere is at least 700 It hotter than the s
urface temperature throughout the atmosphere. This implies that the interac
tion of the Na atoms with the surface is governed by energetic processes. (
C) 1999 Elsevier Science Ltd. All rights reserved.