Synthesis and characterization of monomeric and dimeric palladium(II)-ammonium complexes: their use for the catalytic oxidation of alcohols

Authors
Bouquillon, S d'Hardemare, AD Averbuch-Pouchot, MT Henin, F Muzart, J
Citation
S. Bouquillon et al., Synthesis and characterization of monomeric and dimeric palladium(II)-ammonium complexes: their use for the catalytic oxidation of alcohols, POLYHEDRON, 18(26), 1999, pp. 3511-3516
Citations number
36
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
18
Issue
26
Year of publication
1999
Pages
3511 - 3516
Database
ISI
SICI code
0277-5387(1999)18:26<3511:SACOMA>2.0.ZU;2-6
Abstract
The addition of quaternary ammonium salts, R4NX, to PdCl2 leads to mononucl ear anionic complexes: (R4N)(2)PdX4. A dinuclear complex, (n-Bu4N)(2)Pd2Cl6 , has been characterized from the crystallization of the corresponding mono meric species under controlled conditions. These complexes revealed a simil ar efficiency as mixtures of PdCl2 and R4NX for the catalytic oxidation of alcohols using 1,2-dichloroethane as both solvent and stoichiometric oxidan t. (C) 1999 Elsevier Science Ltd. All rights reserved.