'Ductile' mixed biopolymer gel composites

Citation
Kp. Plucknett et al., 'Ductile' mixed biopolymer gel composites, POLYMER, 41(6), 2000, pp. 2319-2323
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER
ISSN journal
00323861 → ACNP
Volume
41
Issue
6
Year of publication
2000
Pages
2319 - 2323
Database
ISI
SICI code
0032-3861(200003)41:6<2319:'MBGC>2.0.ZU;2-R
Abstract
The deformation and failure behaviour of novel 'pseudo-ductile' gelatin/mal todextrin mixed biopolymer gels have been assessed using dynamic mechanical tests, conducted on the stage of a confocal laser scanning microscope. The se materials exhibit a phase-separated structure, with spherical maltodextr in-rich inclusions within a continuous gelatin-rich matrix. Using both conv entional tension and notched compact tension tests, it was observed that th e apparent ductility was due to inclusion/matrix interfacial debonding, res ulting in reduced elastic modulus. Based upon a simple debonding model, an interfacial fracture energy of similar to 0.25 J m(-2) was determined. (C) 1999 Elsevier Science Ltd. All rights reserved.