Boron carbide is a good material for very hard coatings mechanical applicat
ions. Sintered bulk B4C is one of the hardest known materials (40 GPa), wit
h a high Young's modulus and a very high chemical and thermal stability. In
B4C film deposition, ion bombardment during film growth can deeply affect
the material properties. Films were deposited by tuned RF magnetron sputter
ing from a sintered B4C target, under different conditions of ion bombardme
nt. corresponding to substrate biases varying from +15 to -80 V. Homogeneou
s and stochiometric B4C films were obtained. Their mechanical properties: m
icrohardness, Young's modulus, internal stress and adhesion have been measu
red by the dynamical nanoindentation method, by the beam bending method and
by the microscratch method, respectively. As ion energy is increased, the
stress of the films and the critical load increases, while both microhardne
ss and Young's modulus have maximum values of 30 and 350 GPa respectively,
for a bombarding ion energy of 50 eV. (C) 1999 Elsevier Science S.A. All ri
ghts reserved.