F. Hildebrandt et al., FORMATION OF COLUMNAR MESOPHASES BY ROD-LIKE MOLECULES - FACIAL AMPHIPHILIC P-TERPHENYL DERIVATIVES, Advanced materials, 9(7), 1997, pp. 564
Communication: The liquid-crystalline behavior of rod-like mesogens is
normally associated with the formation of smectic layer structures. H
owever, it is shown that the introduction of large hydrophilic groups
in a lateral position, such as in the Figure, can lead to columnar mes
ophases. The formation of columnar mesophases by rod-like molecules is
suggested to be a more general phenomenon than currently thought.