The ferroelectric properties of calcium modified lead titanate (Pb0.76Ca0.2
4)TiO3 (PTCa) thin films prepared by a sol - gel method with successive cry
stallisations on three different substrates (A) Pt / Ti / SiO2 / Si (100),
(B) Ti / Pt / Ti / SiO2 / Si(100) y (C) Pt / TiO2 / SiO2/Si (100), have bee
n studied. The results of the ferroelectric characterisation show values of
the spontaneous pyroelectric coefficient close to = 5.10(-9) C cm(-2) K-1.
The low switching properties favour the stabilisation in time of the pyroe
lectric coefficient value. A latter annealing thermal treatment (650 degree
s C 1h) produces changes in the ferro - piezoelectric properties that can b
e related with changes in the texture of the films.