Electrochemistry of encapsulated redox centers

Citation
Cm. Cardona et al., Electrochemistry of encapsulated redox centers, CHEM SOC RE, 29(1), 2000, pp. 37-42
Citations number
30
Categorie Soggetti
Chemistry
Journal title
CHEMICAL SOCIETY REVIEWS
ISSN journal
03060012 → ACNP
Volume
29
Issue
1
Year of publication
2000
Pages
37 - 42
Database
ISI
SICI code
0306-0012(200001)29:1<37:EOERC>2.0.ZU;2-0
Abstract
A few examples of molecules containing a redox active core surrounded by an organic sheath have been synthesized recently. The redox nucleus may be at tached covalently to the structure's core or held there by noncovalent forc es. This review article surveys the electrochemical behavior of such redox centers, emphasizing the thermodynamic and kinetic effects brought about by encapsulation.