Kinetic data on the rate of U3O7 formation on UO2 have been critically
reviewed. Oxidation of UO2 powders displays diffusion-controlled (par
abolic) kinetics, whereas sintered UO2 pellets display approximately l
inear kinetics, presumably because the rate of oxidation in the latter
is limited by a combination of cracking, intragranular and grain-boun
dary oxidation. The activation energy for the formation of U3O7 on UO2
is estimated to be 96 kJ mol(-1) for powders and 99 kJ mol(-1) for si
ntered pellets. Analysis of kinetic data suggests that the formation o
f U4O9/U3O7 may have a significant impact on a,eight-gain oxidation ex
periments with used nuclear fuel and should thus be considered when es
timating the rate of U3O8 formation.