While the developments in spectrochemical instrumentation have (for the mos
t part) kept pace with the quantitative challenges of a diversity of applic
ations, the qualitative aspects of spectrochemical analysis lag far behind.
This is, of course, the principal challenge of 'chemical speciation'. It s
eems clear at this point that a paradigm shift is in order if the atomic sp
ectrometry community is to step up and solve the practical problems present
ed by biochemists, nutritionists, geologists, and environmental chemists. W
e present here an outline for progress in this area along with a summary of
recent developments in the area of tunable plasma sources.