An analysis of the dielectrophoretic crossover frequency as a function of m
edium conductivity has been made for submicron spheres with different surfa
ce functionalities. It is shown that the AC electrokinetic behavior of the
particles can be explained by modeling the surface conductivity of the part
icle as the sum of two surface conductance components: one due to charge mo
tion behind the slip plane (the Stern layer) and the other due to charge mo
tion in front of the slip plane. (C) 1999 Academic Press.