Study of 1,5,7-triazabicyclo[4,4,0]dec-5-ene protonation by vibrational spectroscopic methods

Authors
Brzezinski, B Schroeder, G Rybachenko, VI Kozhevina, LI Kovalenko, VV
Citation
B. Brzezinski et al., Study of 1,5,7-triazabicyclo[4,4,0]dec-5-ene protonation by vibrational spectroscopic methods, J MOL STRUC, 516(2-3), 2000, pp. 123-130
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
516
Issue
2-3
Year of publication
2000
Pages
123 - 130
Database
ISI
SICI code
0022-2860(20000125)516:2-3<123:SO1PBV>2.0.ZU;2-#
Abstract
The normal coordinate analysis and calculation of the IR absorption band in tensities have been carried out for 1,5,7-triazabicyclo[4,4,0]dec-5-ene (TB D) and its three possible protonated tautomeric forms. It has been shown th at protonated molecule TBD has only one tautomeric species in which proton is attached to imine nitrogen atom. (C) 2000 Elsevier Science B.V. All righ ts reserved.