NMR study of the complexes of tris(oxaalkyl) borates with SbCl5

Authors
Gierczyk, B Schroeder, G Wojciechowski, G Leska, B Rybachenko, VI Brzezinski, B
Citation
B. Gierczyk et al., NMR study of the complexes of tris(oxaalkyl) borates with SbCl5, J MOL STRUC, 516(2-3), 2000, pp. 153-156
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
516
Issue
2-3
Year of publication
2000
Pages
153 - 156
Database
ISI
SICI code
0022-2860(20000125)516:2-3<153:NSOTCO>2.0.ZU;2-5
Abstract
The complex formation between three tris(oxaalkyl) berates (B2, B3, B4) and SbCl5 as well as the structure of these complexes were studied by calorime tric and NMR methods. Results of the calorimetric titration indicate a depe ndence of Delta H of the reaction heats on the length of the oxaalkyl chain s, and a formation of stable complexes. The H-1 and C-13 NMR data confirmed the formation of the respective stable complexes. The structure of the com plexes is discussed. (C) 2000 Elsevier Science B.V. All rights reserved.