Continuity conditions for a time-dependent wavefunction

Authors
Citation
R. Lefebvre, Continuity conditions for a time-dependent wavefunction, J MOL ST-TH, 493, 1999, pp. 117-123
Citations number
23
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM
ISSN journal
01661280 → ACNP
Volume
493
Year of publication
1999
Pages
117 - 123
Database
ISI
SICI code
0166-1280(199912)493:<117:CCFATW>2.0.ZU;2-A
Abstract
In addition to the usual condition of continuity of the wavefunction and of its derivative with respect to position, continuity with respect to time i s necessary in a solution of the time-dependent Schrodinger equation. For a particle interacting with an oscillatory field, two different procedures t o ensure this continuity are presented and tested. These methods are effici ent to calculate the probabilities for absorption or emission of photons by a particle incident on a potential of arbitrary shape, even in intense fie ld situations. We apply the formalism to an examination of a criterion give n by Buttiker and Landauer to define the time it tal;es for a particle to t unnel through a barrier. (C) 1999 Elsevier Science B.V. All rights reserved .