Structural elucidation of two novel products from the soybean lipoxygenase-catalysed dioxygenation of curcumin

Authors
Toth, G Roth, M Weckerle, B Schreier, P
Citation
G. Toth et al., Structural elucidation of two novel products from the soybean lipoxygenase-catalysed dioxygenation of curcumin, MAGN RES CH, 38(1), 2000, pp. 51-54
Citations number
10
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
MAGNETIC RESONANCE IN CHEMISTRY
ISSN journal
07491581 → ACNP
Volume
38
Issue
1
Year of publication
2000
Pages
51 - 54
Database
ISI
SICI code
0749-1581(200001)38:1<51:SEOTNP>2.0.ZU;2-9
Abstract
The conversion of curcumin by soybean lipoxygenase leads to three stereoiso mers of 2-[(4'-hydroxy-3'-methoxy)phenoxy]-4-(4"-hydroxy-3"-methoxy-(phenyl )-8-hydroxy-6-oxo-3-oxabicyclo[3.3.0]-7-octene. Their structures and confor mational behaviour were elucidated by various H-1 and C-13 NMR methods and high-performance liquid chromatography-electrospray ionization tandem mass spectrometry. Copyright (C) 2000 John Wiley & Sons, Ltd.