The adsorption and growth of Ge on monohydride the Si(001)-(2 x 1) surface
was studied with scanning tunneling microscopy. We observed that Ge monomer
s are stable at three adsorption sites and that the diffusivity of Ge adato
m is reduced relative to on the bare surface, as suggested by the recent fi
rst-principle calculation. With the surfactant effect of hydrogen, we were
able to grow flat Ge overlayers by preventing the growth of hut cluster bey
ond the known critical thickness. The etching effect of hydrogen on the Ge
overlayer was observed. [S0163-1829(99)12147-7].