Nevados de Chilian volcano is a large composite stratovolcanic complex in t
he Southern Volcanic Zone of the Chilean Andes. It is one of the highest-ri
sk volcanoes in Chile due to high levels of historic activity and rapid dev
elopment of economic activity in the area. High precision Ar-40/Ar-39 and C
-14 geochronology, geochemistry and petrology have been employed in additio
n to photogeology and field mapping to elucidate the evolution of this volc
ano and assess its hazards. Nevados de Chilian has been active since at lea
st 640 ka when a large group of subglacial andesite flows were erupted. Sin
ce 100 ka, sequences of andesite and dacite lavas have been erupted into bo
th subaerial and subglacial environments. lgnimbrites were erupted at aroun
d 40 ka and may have been associated with caldera collapses. Two separate e
ruptive centres have evolved since 40 ka: the Cerro Blanco and Las Termas s
ubcomplexes. The two centres are 6 km apart. yet have contemporaneously eru
pted geochemically distinct magmas. Subglacial lavas have been identified o
n the high flanks of the volcano and Ar-40/Ar-39 dating has confirmed their
eruption during recent glaciations (isotope stages 4 and 2). Tephra fall d
eposits have been dated by C-14 analysis of interstratified organic materia
l and indicate that no proximal tephra fallout deposits older than 9 ka rem
ain. Tephra dispersal indicates that Holocene activity has involved vulcani
an to subplinian eruptions. At least, 3 pyroclastic flow eruptions have occ
urred during the Holocene and lahar deposits are common in the valleys arou
nd the volcano. Historically, the Santa Gertrudis vent erupted during 1861-
1865 and the dacite lava cone complexes Nuevo and Arrau were constructed du
ring 1906-1943 and 1973-1986, respectively. Historic records indicate that
lahars and landslides are major hazards to economic developments on the low
er flanks and valleys.