The effects of various extraction conditions on the dynamic extraction of t
he essential oil components carvone and limonene from spearmint leaves usin
g SC-CO2 were investigated. The extraction rate increased with increasing p
ressure or decreasing temperature. An increase of the CO2 flow rate increas
ed the extraction rate but decreased the solvent efficiency of CO2. Ground
leaf samples with a smaller particle size showed an enhanced initial extrac
tion rate for carvone as compared to larger particle size leaf samples. The
use of an ethanol modifier did not enhance the extraction rate but did cau
se the coextraction of pigment and waxy substances.