DSC investigations of the phase transitions of [M(H2O)(6)](NO3)(2), where M = Mn, Co, Ni, Cu and Zn

Citation
E. Mikuli et al., DSC investigations of the phase transitions of [M(H2O)(6)](NO3)(2), where M = Mn, Co, Ni, Cu and Zn, Z NATURFO A, 54(10-11), 1999, pp. 595-598
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN journal
09320784 → ACNP
Volume
54
Issue
10-11
Year of publication
1999
Pages
595 - 598
Database
ISI
SICI code
0932-0784(199910/11)54:10-11<595:DIOTPT>2.0.ZU;2-9
Abstract
The phase transitions of [M(H2O)(6)](NO3)(2), where M = Mn2+, Co2+, Ni2+, C u2+ or Zn2+ have been studied at 100 - 400 K by DSC. Two phase transitions connected with a two-stage melting process have been found for these five c ompounds. For the compound with M = Co, besides the two melting points a so lid-solid phase transition at 272 K has been found.