Study of chemical reaction in nonlinear system S2O82--ClO2--S2-

Authors
Hou, Z Li, YN Wei, QL Chen, L Cai, ZS Zhao, XZ
Citation
Z. Hou et al., Study of chemical reaction in nonlinear system S2O82--ClO2--S2-, ACT CHIM S, 57(12), 1999, pp. 1319-1324
Citations number
9
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
57
Issue
12
Year of publication
1999
Pages
1319 - 1324
Database
ISI
SICI code
0567-7351(1999)57:12<1319:SOCRIN>2.0.ZU;2-Y
Abstract
A new oscillatory system of S2O82- - ClO2- - S2- is reported. The oscillati on of Pt potential in CSTR and other nonlinear phenomena of Pt potential, a nd pH value in close (Batch) system are studied. The autocatalytic procedur es are analyzed, and the stoichiometric equations of several reaction steps are suggested. The analysis of the autocatalytic mechanism is accomplished .