Barrels used for the aging of wines and spirits are constructed from oak he
artwood. Heartwood tannins (soluble polyphenols) are the most abundant of t
he constituents of oak wood that are potentially extracted into the wine du
ring aging. The structure and properties of these compounds are reviewed, a
s are methods of analysis. Studies of the natural variation in the concentr
ation of heartwood tannins are summarized and show that levels are highly v
ariable within and between individual trees and especially between wood pro
venance and species. Despite the abundance of heartwood tannins and their s
olubility in the wines, the concentration in oak-aged wines is generally lo
wer then expected and their influence on wine flavor remains uncertain, Dif
ferent studies and hypotheses concerning the influence of oak tannins durin
g wine aging are reviewed and conclusions drawn on our current understandin
g of their role.