Local and seasonal variations in atmospheric nitrogen dioxide levels at Rothamsted, UK, and relationships with meteorological conditions

As part of the UK Environmental Change Network (ECN), a number of passive n itrogen dioxide (NO2) diffusion tubes were set up at Rothamsted Experimenta l Station in September 1993, Concentrations of atmospheric NO2 recorded bet ween September 1993 and April 1997 are described in terms of seasonal and l ocal spatial variations and in relation to different types of background ve getation. At most sites, NO2 levels fluctuate seasonally: the general patte rn is one of winter highs and summer lows, modified by a slight dip in Dece mber and January and slower changes in May and August. Smoothing splines wi th a trigonometric penalty function are used to describe the periodic seaso nal variation. An adequate summary of patterns of NO2 concentration is obta ined using a common seasonal component of variation, together with local sp atial variations in the mean level and the amplitude of the seasonal fluctu ations. The presence of trees reduces the mean NO2 level and the amplitude of the seasonal variation, while proximity to road traffic and dense vegeta tion increases the mean level and almost eliminates seasonal variation. The effect of traffic decreases rapidly with distance from the road. Associati ons between NO2 levels and local meteorological conditions are also investi gated. Levels of NO2 are generally unrelated to meteorological conditions, suggesting that they are mainly driven by changes in background inputs, suc h as those associated with the nearby town of Harpenden, A weak negative as sociation was observed between NO2 concentration and wind speed. This sugge sts that unseasonably high wind speeds decrease concentrations of NO2. Non- linearity in the relationship between NO2 levels and wind speed is accounte d for by the effects of extreme wind speeds on the diffusion lengths of the tubes. (C) 2000 Elsevier Science Ltd. All rights reserved.