Trace metal chemistry of particulate aerosols from the UK mainland coastalrim of the NE Irish sea

Data are provided on the long-term average trace metal composition of aeros ols collected at two urban (Liverpool and Preston) and one rural (Lancaster ) site on the UK mainland coastal rim of the NE Irish Sea. There are variat ions in the trace metal composition of aerosols at the urban and rural site s, with evidence of local urban 'hot spot' sources of Ni, Zn and Cr. Data f rom the three sites are combined to give an average trace metal composition of the aerosol at the NE Irish Sea UK coastal sites, This aerosol has high er average concentrations and EFcrust values for some trace metals, e.g. Ni and Cr, than those at other Western European coastal sites but, relative t o crustal material, there is general 'uniformity of composition' in the ext ent to which Ni, Cr, Cu, Zn and Pb are enriched in all the coastal aerosols . To estimate the composition of the aerosol transported to the NE Irish Se a across the UK mainland coast, the coastal strip is partitioned into urban and rural regions and an average trace metal composition for the 'whole ri m' aerosol is given. This is used to make an 'upper limit' estimate of the trace metal composition of the aerosol transported to open-sea regions of t he NE Irish Sea, which shows a generally similar enrichment of trace metals , relative to crustal material, as that of the North Sea aerosol. (C) 2000 Elsevier Science Ltd. All rights reserved.