F. Kunkel et al., PHOSPHORANE IMINATO COMPLEXES OF SULFUR - CRYSTAL-STRUCTURES OF [S(NPET3)(3)]CL, [S(NPET3)(2)]CL-2 AND [ME3SIOSO2NPPH3], Zeitschrift fur anorganische und allgemeine Chemie, 623(6), 1997, pp. 962-966
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
The ionic phosphorane iminato complexes which is known from literature
data, were characterized by crystal structure determinations. [S(NPEt
3)(3)]Cl and [S(NPEt3)(2)]Cl-2 are obtained as colourless, moisture se
nsitive crystals after reaction of Me3SiNPEt3 with disulfur dichloride
from acetonitrile solutions. Both complexes, as well as the molecular
complex [Me3SiOSO2NPPh3], which is known from literature data, were c
haracterized by crystal structure determinations.