The porous SiO2 xerogels with controlled structure were obtained from TEOS
in the presence of PEG by sol-gel method. The results showed that PEG restr
ained the hydrolysis reaction of TEOS, and then modified the surface of sol
particle to form the PEG-clusters (i. e. the ring-like networks in short o
rder). As a result, the addition of PEG could adjust the texture properties
of SiO2 xerogels, It has been found that the SiO2 xerogel has a stronger f
lexible skeleton, narrower pore distribution, and higher thermal stability
with the removal of the residue organic(such as PEG and so on) by vacuum he
at-treatment.